Investigation of titanium nanoparticles-reinforced Asphalt Composites Using Rheological Tests

Authors

  • Paulo Germano Tavares Marinho Filho Federal University of Campina Grande, Paraiba – Brazil
  • Lêda Christiane de Figueirêdo Lopes Lucena Federal University of Campina Grande, Paraíba – Brazil
  • Matheus Costa Lopes Federal University of Campina Grande, Paraíba – Brazil

DOI:

https://doi.org/10.14295/transportes.v30i2.2614

Keywords:

Nanomaterial, Modified binder, Binder rheological evaluation, Oleylamine

Abstract

Asphalt binder modification techniques are beneficial for the performance improvement of roads because they can be durable, present less permanent deformation, and provide longer fatigue life. The main modification agents involved in this process are polymers, fillers, fibers, and, more recently, nanomaterials, which have presented technical and economic feasibility. The nanoparticles were added to the base asphalt binder at a concentration of 3% of weight in pure and surface-modified states. This study aims to analyze the effect of surface modification of titanium dioxide nanoparticles using three different agents: oleic acid, benzyl alcohol, and oleylamine. The results have indicated that surface modification of the nanoparticles with oleylamine improved the interaction between the particles and the binder, contributing to increasing fatigue life and resistance to permanent deformation and delaying the aging process. Furthermore, the results of rheological tests have indicated that incorporating nanoparticles surface-modified with oleylamine into modified asphalt binder 55/75-E and asphalt binder 50/70 has produced higher resistance to the aging process less susceptibility to permanent deformation and cracks.

Downloads

Download data is not yet available.

Author Biography

Lêda Christiane de Figueirêdo Lopes Lucena, Federal University of Campina Grande, Paraíba – Brazil

Departamento de Engenharia Civil. Universidade Federal de Campina Grande.

References

AASHTO (2010) M 320-10: Standard Specification for: Performance-Graded Asphalt Binder. Washington, D.C.: American Association of State Highway and Transportation Officials.

AASHTO (2012) TP 101: Standard Method of Test for Estimating Fatigue Resistance of Asphalt Binders Using the Linear Amplitude Sweep. Washington, D.C.: American Association of State Highway and Transportation Officials.

AASHTO (2021) M 332: Standard Specification for Performance-Graded Asphalt Binder Using Multiple Stress Creep Recovery (MSCR) Test. Washington, D.C.: American Association of State Highway and Transportation Officials.

Alcântara, G. B. (2007) Nanopartículas de maguemita complexadas com ácido oleico. Dissertation (Master in Physics). IF - Programa de Pós-Graduação, Universidade de Brasília. Brasília. Available at: https://repositorio.unb.br/handle/10482/1459 (Accessed: 01 Jul 2022).

ASTM (2006) D36: Standard Test Method for Softening Point of Bitumen (Ring-and-Ball Apparatus). West Conshohocken: American Society for Testing and Materials.

ASTM (2013) D5: Standard Test Method for Penetration of Bituminous Materials. West Conshohocken: American Society for Testing and Materials.

ASTM (2015a) D4402: Standard Test Method for Viscosity Determination of Asphalt at Elevated Temperatures Using a Rotational Viscometer. West Conshohocken: American Society for Testing and Materials.

ASTM (2015b) D7405-15: Standard Test Method for Multiple Stress Creep and Recovery (MSCR) of Asphalt Binder Using a Dynamic Shear Rheometer. West Conshohocken: American Society for Testing and Materials.

ASTM (2016) D6373: Standard Specification for Performance-Graded Asphalt Binder. West Conshohocken: American Society for Testing and Materials.

ASTM (2018) D6084: Standard Test Method for Elastic Recovery of Asphalt Materials by Ductilometer. West Conshohocken: American Society for Testing and Materials.

Beck Júnior, W. (2011) Nanopartículas magnéticas metálicas recobertas com óxido de ferro: intensificação das propriedades magnéticas da nanopartícula e funcionalização para aplicação em biomedicina. Dissertation (Master in Science). Instituto de Química de São Carlos, Universidade de São Paulo. São Carlos. DOI: 10.11606/d.75.2011.tde-02052011-144102.

Faruk, A. N. M. et al. (2014) “Application of Nano-Technology in Pavement Engineering: A Literature Review” in Application of Nanotechnology in Pavements, Geological Disasters, and Foundation Settlement Control Technology. American Society of Civil Engineers, pp. 9–16. DOI: 10.1061/9780784478448.002.

Golestani, B. et al. (2015) “Nanoclay application to asphalt concrete: Characterization of polymer and linear nanocomposite-modified asphalt binder and mixture” Construction and Building Materials, 91, pp. 32–38. DOI: 10.1016/j.conbuildmat.2015.05.019.

Hassan, M. M. et al. (2012) “Laboratory Evaluation of Environmental Performance of Photocatalytic Titanium Dioxide Warm-Mix Asphalt Pavements” Journal of Materials in Civil Engineering, 24(5), pp. 599–605. DOI: 10.1061/(asce)mt.1943-5533.0000408.

Hintz, C. and Bahia, H. (2013) “Simplification of Linear Amplitude Sweep Test and Specification Parameter” Transportation Research Record, 2370(1), pp. 99–106. DOI: 10.3141/2370-02.

Hong, R. Y. et al. (2009) “Synthesis, surface modification and photocatalytic property of ZnO nanoparticles” Powder Technology, 189(3), pp. 426–432. DOI: 10.1016/j.powtec.2008.07.004.

Johnson, C. M. and Bahia, H. U. (2010) “Evaluation of an Accelerated Procedure for Fatigue Characterization of Asphalt Binders” Road Materials and Pavement Design. Available at: https://uwmarc.wisc.edu/files/linearamplitudesweep/RMPD10_LAS_CMJ_HB-100321.pdf (Accessed: 01 Jul 2022).

Li, G.-Y. et al. (2008) “Preparation and properties of magnetic Fe3O4–chitosan nanoparticles” Journal of Alloys and Compounds, 466(1–2), pp. 451–456. DOI: 10.1016/j.jallcom.2007.11.100.

Li, R. et al. (2017) “Developments of nano materials and technologies on asphalt materials – A review” Construction and Building Materials, 143, pp. 633–648. DOI: 10.1016/j.conbuildmat.2017.03.158.

Magalhães, M. J. M. (2014) Síntese e modificação da superfície de nanocristais semicondutores para aplicação como sondas fluorescentes em meio não-aquoso. Dissertation (Master in Quality Control). Faculdade de Farmácia, Universidade do Porto. Porto. Available at: https://repositorio-aberto.up.pt/bitstream/10216/77261/2/33381.pdf (Accessed: 01 Jul 2022).

Mahali, I. and Sahoo, U. C. (2019) “Rheological characterization of Nanocomposite modified asphalt binder” International Journal of Pavement Research and Technology, 12(6), pp. 589–594. DOI: 10.1007/s42947-019-0070-8.

Marinho Filho, P. G. T. (2017) Avaliação reológica de ligantes asfálticos modificados com nanopartículas de dióxido de titânio. Dissertation (Master in Civil and Environmental Engineering). Programa de Pós-Graduação em Engenharia Civil e Ambiental, Universidade Federal de Campina Grande. Campina Grande. Available at: http://dspace.sti.ufcg.edu.br:8080/jspui/handle/riufcg/374 (Accessed: 01 Jul 2022).

Medeiros, I. A. F. de (2018) Nanoestruturação de Ferritas de Cobalto (CoxFe3-xO4): efeito sobre a catálise e sobre a detecção de gases poluentes. Thesis (PhD in Chemical Engineering). Programa de Pós-Graduação em Engenharia Química, Universidade Federal do Rio Grande do Norte. Natal. Available at: https://repositorio.ufrn.br/jspui/handle/123456789/26212 (Accessed: 01 Jul 2022).

Mourdikoudis, S. and Liz-Marzán, L. M. (2013) “Oleylamine in Nanoparticle Synthesis” Chemistry of Materials. American Chemical Society, 25(9), pp. 1465–1476. DOI: 10.1021/cm4000476.

NCHRP (2001) Report 459 - Characterization of Modified Asphalt Binders in Superpave Mix Design. Washington, D.C.: National Cooperative Highway Research Program.

Olsen, R. E. (2013) Synthesis, characterization, and application of high surface area, mesoporous, stabilized anatase TiO2 catalyst supports. Dissertation (Doctor of Philosophy). Department of Chemistry and Biochemistry, Brigham Young University. Provo. Available at: http://hdl.lib.byu.edu/1877/etd6632 (Accessed: 01 Jul 2022).

Possebon, É. P. (2021) Caracterização avançada de ligantes e misturas asfálticas brasileiras. Thesis (PhD in Civil Engineering). Programa de Pós-Graduação em Engenharia Civil, Universidade Federal de Santa Maria. Santa Maria. Available at: http://repositorio.ufsm.br/handle/1/22487 (Accessed: 01 Jul 2022).

Rong, M. Z., Zhang, M. Q. and Ruan, W. H. (2006) “Surface modification of nanoscale fillers for improving properties of polymer nanocomposites: a review” Materials Science and Technology, 22(7), pp. 787–796. DOI: 10.1179/174328406x101247.

Shafabakhsh, G., Mirabdolazimi, S. M. and Sadeghnejad, M. (2014) “Evaluation the effect of nano-TiO2 on the rutting and fatigue behavior of asphalt mixtures” Construction and Building Materials, 54, pp. 566–571. DOI: 10.1016/j.conbuildmat.2013.12.064.

Sobreiro, F. P. (2015) Efeito da adição de ácidos fosfóricos no comportamento reológico de ligantes asfálticos puros e modificados com copolímero SBS. Thesis (PhD in Science). Escola de Engenharia de São Carlos, Universidade de São Paulo. São Carlos. DOI: 10.11606/t.18.2014.tde-28052014-100359.

Sousa Neto, V. F. de (2019) Avaliação reológica do ligante asfáltico modificado com nanopartículas de óxido de zinco. Dissertation (Master in Civil and Environmental Engineering). Programa de Pós-Graduação em Engenharia Civil e Ambiental, Universidade Federal de Campina Grande. Campina Grande. Available at: http://dspace.sti.ufcg.edu.br:8080/jspui/handle/riufcg/3342 (Accessed: 01 Jul 2022).

Tanzadeh, J. et al. (2012) “Laboratory Study on the Effect of Nano TiO2 on Rutting Performance of Asphalt Pavements” Advanced Materials Research, 622–623, pp. 990–994. DOI: 10.4028/www.scientific.net/amr.622-623.990.

Viali, W. R. (2009) Síntese e Caracterização de nanopartículas de maghemita revestidas com ácido oléico para obtenção de fluidos magnéticos a base de óleos isolantes. Dissertation (Master in chemistry). Instituto de Química, Universidade Federal de Goiás. Goiânia. Available at: http://repositorio.bc.ufg.br/tede/handle/tde/1059 (Accessed: 01 Jul 2022).

Wang, L. S. and Hong, R. Y. (2011) “Synthesis, Surface Modification and Characterisation of Nanoparticles”, in B. Reddy (ed.), Advances in Nanocomposites - Synthesis, Characterization and Industrial Applications, IntechOpen, London. DOI: 10.5772/10540.

Yang, S. et al. (2018) “Ultraviolet and PAV aging procedures influence on rheological characteristics of Sasobit/SBS modified binder containing titanium dioxide nanoparticles” Petroleum Science and Technology, 36(19), pp. 1524–1530. DOI: 10.1080/10916466.2018.1476535.

You, L. et al. (2018) “Assessment of nanoparticles dispersion in asphalt during bubble escaping and bursting: Nano hydrated lime modified foamed asphalt” Construction and Building Materials, 184, pp. 391–399. DOI: 10.1016/j.conbuildmat.2018.06.234.

You, Z. et al. (2011) “Nanoclay-modified asphalt materials: Preparation and characterization” Construction and Building Materials, 25(2), pp. 1072–1078. DOI: 10.1016/j.conbuildmat.2010.06.070.

Zhang, H. et al. (2015) “Influence of surface modification on physical and ultraviolet aging resistance of bitumen containing inorganic nanoparticles” Construction and Building Materials, 98, pp. 735–740. DOI: 10.1016/j.conbuildmat.2015.08.138.

Imagem da capa, volume 30, número 2

Downloads

Published

2022-08-31

How to Cite

Tavares Marinho Filho, P. G. ., de Figueirêdo Lopes Lucena, L. C. ., & Costa Lopes, M. . (2022). Investigation of titanium nanoparticles-reinforced Asphalt Composites Using Rheological Tests. TRANSPORTES, 30(2), 2614. https://doi.org/10.14295/transportes.v30i2.2614

Issue

Vol. 30 No. 2 (2022)

Section

Artigos

License

Copyright (c) 2022 Paulo Germano Tavares Marinho Filho, Lêda Christiane de Figueirêdo Lopes Lucena, Matheus Costa Lopes

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Authors who submit papers for publication by TRANSPORTES agree to the following terms:

  1. Authors retain copyright and grant TRANSPORTES the right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.

  2. Authors may enter into separate, additional contractual arrangements for the non-exclusive distribution of this journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in TRANSPORTES.

  3. Authors are allowed and encouraged to post their work online (e.g., in institutional repositories or on their website) after publication of the article. Authors are encouraged to use links to TRANSPORTES (e.g., DOIs or direct links) when posting the article online, as TRANSPORTES is freely available to all readers.

  4. Authors have secured all necessary clearances and written permissions to published the work and grant copyright under the terms of this agreement. Furthermore, the authors assume full responsibility for any copyright infringements related to the article, exonerating ANPET and TRANSPORTES of any responsibility regarding copyright infringement.

  5. Authors assume full responsibility for the contents of the article submitted for review, including all necessary clearances for divulgation of data and results, exonerating ANPET and TRANSPORTES of any responsibility regarding to this aspect.